全文获取类型
收费全文 | 712篇 |
免费 | 75篇 |
国内免费 | 193篇 |
专业分类
安全科学 | 101篇 |
废物处理 | 26篇 |
环保管理 | 61篇 |
综合类 | 361篇 |
基础理论 | 241篇 |
污染及防治 | 81篇 |
评价与监测 | 19篇 |
社会与环境 | 79篇 |
灾害及防治 | 11篇 |
出版年
2024年 | 5篇 |
2023年 | 14篇 |
2022年 | 28篇 |
2021年 | 28篇 |
2020年 | 30篇 |
2019年 | 30篇 |
2018年 | 24篇 |
2017年 | 33篇 |
2016年 | 32篇 |
2015年 | 46篇 |
2014年 | 35篇 |
2013年 | 90篇 |
2012年 | 66篇 |
2011年 | 93篇 |
2010年 | 50篇 |
2009年 | 45篇 |
2008年 | 39篇 |
2007年 | 43篇 |
2006年 | 38篇 |
2005年 | 22篇 |
2004年 | 22篇 |
2003年 | 33篇 |
2002年 | 20篇 |
2001年 | 22篇 |
2000年 | 17篇 |
1999年 | 17篇 |
1998年 | 11篇 |
1997年 | 12篇 |
1996年 | 7篇 |
1995年 | 4篇 |
1994年 | 7篇 |
1993年 | 6篇 |
1992年 | 2篇 |
1991年 | 1篇 |
1990年 | 2篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1975年 | 1篇 |
1971年 | 2篇 |
1970年 | 1篇 |
排序方式: 共有980条查询结果,搜索用时 15 毫秒
11.
Liu Zhengchao Pan Xunxi Dong Wenbo Hou Huiqi Zhang Zhenman Hou Jian Yu Yong Li Changlin 《环境科学学报(英文版)》1997,9(1):95-99
In this paper pulsed corona discharge is shown to be effective for the decomposition of CF3Cl(Freon-13).The pressure of CF3Cl was 2.67×103Pa,after discharged for 2 min,39.5% of CF3Cl was decomposed.The products were mainly CF4,Cl2 and CF2Cl2.The yield increased by adding O2 or air.Under the same conditions,more than 94% decomposition yield was obtained if 5.32×103Pa O2 or air was added.The composition of products became CF2O,Cl2 and CF4.While the partial pressure of O2 or air reached 1 arm,the decomposition yield decreased to 54.5% and 48. 5% respectively. 相似文献
12.
The preparation of immobilizing-catalysts for decomposing ozone by using dipping method was studied. XRD, XPS and TEM were used to characterize the catalysts. The three kinds of catalysts were selected preferentially, and their catalytic activities were investigated. The results showed that the catalyst with activated carbon dipping acetate( active components are Mn:Cu = 3:2, active component proportion in catalyst is 15%, calcination temperature is 200℃ ) has the best catalytic activity for ozone decomposing. One gram of catalyst can decompose 17.6g ozone at initial ozone concentration of 2.5g/m^3 and the residence time in reactor of 0.1s. The experimental results also indicated that humidity of reaction system had negative effect on catalytic activity. 相似文献
13.
Decomposition mass loss and pyrolysis products analyses of particles sampled at various locations along the tailpipe of a Euro-IV diesel engine were performed using a thermogravimetry in conjunction with Fourier transformation infrared spectrometry-mass spectrum. Diesel particles were collected at the same location with and without diesel oxidation catalyst (DOC) mounted on the test engine separately. The three poles in thermal gravity-differential thermal gravity images suggested that the decomposition process of diesel particles could be divided into three stages which correspond to the decompositions of lower boiling substances, higher boiling substances and soot respectively. It is noticed that no matter whether DOC was mounted or not, the further the particles were sampled away from the engine block, the lower the peak temperatures and the heavier the mass losses within the first two stages, which indicated that the soluble organic fraction in the particle samples increased and therefore lowering the activation energy of thermal decomposition. Hydroxyl, ammonia, CxHy fragments, benzene, toluene, and phenol were found to be the primary products of particle decomposition, which didn't change with the location of particle sample point. The employment of DOC increased the activation energy for particle oxidation and resulted in a higher peak temperature and lower mass loss within the first-stage. Moreover, the CO stretching bands of aldehyde and ketone at 1771 cm?1 was only detected without a DOC, while the NO2 peak at 1634 cm?1 was solely noticed with the presence of DOC. Compared to the first-stage pyrolysis products, more polycyclic aromatic hydrocarbons and less CxHy fragments were seen in the second-stage. 相似文献
14.
《环境科学学报(英文版)》2023,35(3):340-348
In recent years, near surface ozone pollution, has attracted more and more attention, which necessitates the development of high efficient and low cost catalysts. In this work, CuO/Cu2O heterojunctioned catalyst is fabricated by heating Cu2O at high temperature, and is adopted as ozone decomposition catalyst. The results show that after Cu2O is heated at 180°C conversion of ozone increases from 75.2% to 89.3% at mass space velocity 1,920,000 cm3/(g·hr) in dry air with 1000 ppmV ozone, which indicates that this heterojunction catalyst is one of the most efficient catalysts reported at present. Catalysts are characterized by electron paramagnetic resonance spectroscopy and ultraviolet photoelectron spectroscopy, which confirmed that the heterojunction promotes the electron transfer in the catalytic process and creates more defects and oxygen vacancies in the CuO/Cu2O interfaces. This procedure of manufacturing heterostructures would also be applicable to other metal oxide catalysts, and it is expected to be more widely applied to the synthesis of high-efficiency heterostructured catalysts in the future. 相似文献
15.
16.
贫燃条件下汽车尾气中NOx催化净化研究进展 总被引:2,自引:0,他引:2
汽车尾气排放的NOx(主要是NO)是城市大气的主要污染源之一。本综述了近l0年来贫燃条件下NOx催化转化为N2的催化剂研究进展。这些方法包括HC-SCR、NO直接催化分解、NOx吸附-还原等。讨论了不同催化剂的性能影响因素。新的负载材料MFI、MCM-41、SAPO-34的应用增强了催化剂的性能。双功能催化剂由于两种活性位的协同作用表现出较高的活性和选择性。新的纳米结构概念催化剂NOx吸附还原中发现有广泛应用。介绍了上述催化脱除NOx的各种机理并指出了今后研究的方向。 相似文献
17.
18.
进行网络抗震可靠性分析的目的,不仅在于定量评价生命线工程网络系统的抗震性能,更重要的是利用这种分析工具指导网络抗震性能的优化设计。以无向边权网络系统为分析对象,分别以管网造价和系统抗震可靠度作为优化目标和约束条件,建立网络系统拓扑优化模型,利用递推分解算法作为网络系统抗震可靠性分析工具,并引入系统单元的灵敏度分析,采用遗传算法求解网络系统的拓扑优化问题,从而发展了一类工程网络抗震优化设计方法。实例分析结果表明,网络系统拓扑结构与系统可靠度之间有显著的正相关关系。 相似文献
19.
采用先进的绝热加速量热仪为手段,对二甲亚砜的热稳定性进行了系统研究,其内容涉及纯二甲亚砜的热稳定性、加酸碱和硫化物等杂质后二甲亚砜的热稳定性,包括初始放热温度、温升速率、温度-压力等;通过修正试验数据,消除了热惰性因子的影响;得到了二甲亚砜的热稳定性特性。研究表明,在酸、碱存在时,二甲亚砜在室温下即可发生强烈的放热反应,导致二甲亚砜的分解温度提前。该实验研究结果,对二甲亚砜的安全生产工艺过程控制具有重要参考价值。 相似文献
20.
垃圾填埋场有机污染物的生物降解机理 总被引:3,自引:0,他引:3
概述了垃圾填埋场中微生物的作用特性,微生物对有机污染物的降解及其影响因素,介绍了有机污染物降解的两种生化动力学模型:“速度指数模型”和“双曲线速度模型”,以及垃圾降解的动力学方程。 相似文献